Angelina Jolie and Brad Pitt
The couple became instant trending topics – and left fans in shock – on September 19, 2016, when Angelina filed for divorce from Brad citing "irreconcilable differences."
The pair met in 2004, while working together on the film
Mr. and Mrs. Smith. Brad and Angie were engaged in 2012, and secretly tied the knot in August 2014.
The actors are parents to six children, Maddox, Pax, Zahara, Shiloh, and twins Knox and Viviennne.
Photo: Jeffrey Mayer/WireImage